DUGiDocsA novel carbene ruthenium complex as reusable and selective two-electron catalyst for alkene epoxidation
dc.contributor.author
dc.date.accessioned
2015-12-15T11:33:28Z
dc.date.available
2015-12-15T11:33:28Z
dc.date.issued
2011-02-11
dc.identifier.issn
1615-4150
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dc.description.abstract
A new ruthenium aquo catalyst with the formula trans-[Ru(II)(CN-Me)(trpy) OH2](PF6)2 [where trpy=2,2a:6′,2″- terpyridine and CN-Me=3-methyl-1-(pyridin-2-yl)-imidazolylidene] has been prepared and thoroughly characterized by spectroscopic and electrochemical techniques. The complex has been tested in epoxidation catalysis both in dichloromethane and dichloromethane:ionic liquid media, displaying excellent performances and selectivities. Reuse of the catalyst in ionic liquid:solvent media has been explored for the first time in ruthenium-mediated epoxidation catalysis and its performance is fully maintained for up to ten runs
dc.description.sponsorship
This project has been financed by MICINN of Spain through projects CTQ2007-60476/PPQ, CTQ2010-21532-C02-01 and CTQ2009-08328
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application/pdf
dc.language.iso
eng
dc.publisher
Wiley-VCH Verlag
dc.relation
info:eu-repo/grantAgreement/MICINN//CTQ2010-21532-C02-01/ES/MIMETIZACION DE PROCESOS BIOINORGANICOS Y APLICACIONES CATALITICAS CON COMPUESTOS DE METALES DE TRANSICION./
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Reproducció digital del document publicat a: http://dx.doi.org/10.1002/adsc.201000686
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© Advanced Synthesis and Catalysis, 2011, vol. 353, núms. 2-3, p. 231-238
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Articles publicats (D-Q)
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Tots els drets reservats
dc.subject
dc.title
A novel carbene ruthenium complex as reusable and selective two-electron catalyst for alkene epoxidation
dc.type
info:eu-repo/semantics/article
dc.rights.accessRights
info:eu-repo/semantics/embargoedAccess
dc.embargo.terms
Cap
dc.date.embargoEndDate
info:eu-repo/date/embargoEnd/2026-01-01
dc.type.version
info:eu-repo/semantics/publishedVersion
dc.identifier.doi
dc.identifier.idgrec
013362
dc.contributor.funder
dc.relation.ProjectAcronym
dc.identifier.eissn
1615-4169